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Efficient flower-like ZnSe/CuZnS photocatalyst for hydrogen production application

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 9,   Pages 1301-1310 doi: 10.1007/s11705-022-2295-3

Abstract: In this work, a high-efficiency flower-like ZnSe/Cu<sub>0.08sub>Zn<sub>0.92sub>S photocatalyst wasbuilt-in electric field in the heterojunction enhanced light absorption and utilization by the ZnSe/Cu<sub>0.08sub>Zn<sub>0.92sub>S microflowers, accelerated the separation and transfer of photogeneratedThus the photocatalytic hydrogen production ability of the ZnSe/Cu<sub>0.08sub>Zn<sub>0.92sub>S microflowersThe highly stable ZnSe/Cu<sub>0.08sub>Zn<sub>0.92sub>S microflowers could provide excellent catalysis

Keywords: photocatalysis     Cu<sub>0.08sub>Zn<sub>0.92sub>S     ZnSe     hydrogen production    

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Frontiers in Energy 2023, Volume 17, Issue 5,   Pages 654-663 doi: 10.1007/s11708-023-0885-5

Abstract: In this paper, a broad spectrum responsive In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunctionis constructed by in-situ integrating Bi<sub>2sub>S<sub>3sub> with the In<sub>2sub>S<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction demonstrates a rate of 0.71 mmol/(g∙h), which is 2.2 and 1.7 times as much as those of In<sub>2sub>S<sub>3sub> (0.32 mmol/(g∙h) and Bi<sub>2sub>S<sub>3sub> (0.41 mmol/(g∙h)), respectively.

Keywords: photocatalytic hydrogen production     wide-spectrum response     metal sulfides     MOFs derivative     heterogeneous interfacial contact    

NO<sub>xsub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

Frontiers in Energy 2021, Volume 15, Issue 1,   Pages 4-13 doi: 10.1007/s11708-020-0804-y

Abstract: China to control NO emission; thus, it is necessary to understand the formation mechanism of NO and H SThis paper focused on the investigation of reductive gases in the formation of NO and H S in the reductiveinto GE was found to increase not only the coal conversion but also the concentrations of CO and H SBoth the CO and H S concentrations inblended coal combustion increase with an increase in the combustionBased on accumulated experimental data, one interesting finding was that NO and H S from blended coal

Keywords: blended coal combustion     NO<sub>x sub>formation     H<sub>2sub>S formation     air staged combustion    

Removal of P<sub>4sub>, PH<sub>3sub> and H<sub>2sub>S from Yellow Phosphoric Tail Gas by a Catalytic

Ning Ping,Hans-Jörg Bart,Wang Xueqian,Ma Liping,Chen Liang

Strategic Study of CAE 2005, Volume 7, Issue 6,   Pages 27-35

Abstract: and activated carbon proved to be effective catalysts in the catalytic oxidation process (COP) for H<sub>2sub>S and PH<sub>3sub> removal.

Keywords: catalyst     catalytic oxidation     H<sub>2sub>S     P<sub>4sub>     PH<sub>3sub>     fixed bed    

Photoelectrocatalytic generation of H and S from toxic HS by using a novel BiOI/WO nanoflake array photoanode

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 744-751 doi: 10.1007/s11708-021-0775-7

Abstract: In this paper, a photoelectrocatalytic (PEC) recovery of toxic H<sub>2sub>S into H<sub>2sub> andS system was proposed using a novel bismuth oxyiodide (BiOI)/ tungsten trioxide (WO<sub>3sub>) nano-flake>2sub>S totally converted S2– into S without any polysulfide (sub>2sub>S splitting system provides an efficient and sustainable route to recoverH<sub>2sub> and S.

Keywords: bismuth oxyiodide (BiOI)/ tungsten trioxide (WO<sub>3sub>) nano-flake arrays (NFA)     photoelectrocatalytic(PEC)     H<sub>2sub>S splitting     H<sub>2sub>     S    

Sulfur-deficient CoNi<sub>2sub>S<sub>4sub> nanoparticles-anchored porous carbon nanofibers as bifunctional

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1707-1717 doi: 10.1007/s11705-023-2308-x

Abstract: high overpotential and slow kinetics in water splitting, N-doped porous carbon nanofibers-coupled CoNi<sub>2sub>S<sub>4sub> nanoparticles are prepared as bifunctional electrocatalyst.>2sub>S<sub>4sub>.>2sub>S<sub>4sub> from 1.68 to 0.52 eV.Moreover, the uniform distribution of CoNi<sub>2sub>S<sub>4sub> nanoparticles on carbon nanofibers

Keywords: nanoparticle     sulfur vacancy     porous carbon nanofiber     transition metal sulfides     electrolysis    

Inexpensive synthesis of a high-performance Fe

Imran, Muhammad S. Haider, Hee Taik Kim

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 3,   Pages 405-416 doi: 10.1007/s11705-016-1579-x

Abstract: A sol-gel technique has been developed for the synthesis of a magnetite-silica-titania (Fe O -SiO -TiO ) tertiary nanocomposite with improved photocatalytic properties based on the use of inexpensive titania and silica precursors. The exceptional photocatalytic activity of the resulting materials was demonstrated by using them to photocatalyze the degradation of methylene blue solution. The best formulation achieved 98% methylene blue degradation. An interesting feature of the present work was the ability to magnetically separate and reuse the catalyst. The efficiency of the catalyst remained high during two reuses. The synthesized nanomaterials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, ultra-violet-visible spectroscopy, diffuse reflectance spectroscopy, and thermogravimetric analysis. XRD analysis revealed the formation of multicrystalline systems of cubic magnetite and anatase titania crystals. SEM and TEM characterization revealed well-developed and homogeneously dispersed particles of size less than 15 nm. FTIR spectra confirmed the chemical interaction of titania and silica. It was further noticed that the optical properties of the prepared materials were dependent on the relative contents of their constituent metal oxides.

Keywords: sol-gel     photocatalysis     magnetic recovery     TiO<sub>2sub>     Fe<sub>3sub>O<sub>4sub>     SiO<sub>2sub>    

Accounting for the uncertainties in the estimation of average shear wave velocity using – correlations

Frontiers of Structural and Civil Engineering 2021, Volume 15, Issue 5,   Pages 1199-1208 doi: 10.1007/s11709-021-0749-1

Abstract: analysis to estimate the value of V <sub>Ssub>.>Ssub> calculations.>Ssub> at different depths.The scattering nature of the V <sub>Ssub> values estimated using different V <sub>SS30sub> using general and soil-specific correlations.

Keywords: uncertainties     V <sub>Ssub>– N correlations     V <sub>S30sub>     SPT data     statistical    

Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1561-1571 doi: 10.1007/s11705-021-2089-z

Abstract: In this study, we demonstrate the fabrication of three-dimensionally ordered macroporous SrTiO<sub>3sub> decorated with Zn<sub>xsub>Cd<sub>1−sub><sub>xsub>S nanoparticles for hydrogenapparent quantum efficiency of 35.9% at 420 nm, which is 4.2 and 23.9 times higher than those of pure Zn<sub>0.5sub>Cd<sub>0.5sub>S (4.67 mmol·g−1·h−1) and CdS (0.82 mmol·g−1

Keywords: three-dimensionally ordered macroporous SrTiO<sub>3sub>     Zn<sub>xsub>Cd<sub>1–sub><sub>xsub>S     visible light     hydrogen production     promotion mechanism    

China’s pre-2020 CO

Hailin WANG

Frontiers in Energy 2019, Volume 13, Issue 3,   Pages 571-578 doi: 10.1007/s11708-019-0640-0

Abstract: The results show that China’s CO intensity of GDP in 2020 is expected to fall by 52.9%–54.4% than theChina’s CO intensity of GDP in 2030 will fall by over 70% than that in 2005, and CO emissions peak

Keywords: China’s National Determined Contribution     emission reduction potential     scenario analysis     CO<sub>2sub    

Highly effective visible-photocatalytic hydrogen evolution and simultaneous organic pollutant degradation over an urchin-like oxygen-doped MoS/ZnInS composite

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 10, doi: 10.1007/s11783-022-1566-z

Abstract:

● An urchin-like OMS/ZIS composite was fabricated by a facile solvothermal method.

Keywords: Dual-functional photocatalysts     Oxygen-doped MoS<sub>2sub>/ZnIn<sub>2sub>S<sub>4sub>     H<sub>2sub> evolution     Organic pollutant    

Impacts of emissions and meteorological changes on China’s ozone pollution in the warm seasons of 2013

Dian Ding, Jia Xing, Shuxiao Wang, Xing Chang, Jiming Hao

Frontiers of Environmental Science & Engineering 2019, Volume 13, Issue 5, doi: 10.1007/s11783-019-1160-1

Abstract: O3 increment is mainly caused by changes in meteorology rather than emissions. Emission reduction is effective to reduce O3 nationwide, especially in summer. Strengthened NOx controls are necessary to meet the ambient O3 standard. We have quantified the impacts of anthropogenic emissions reductions caused by the Air Pollution Control Action Plan and changes in meteorological fields between 2013 and 2017 on the warm-season O3 concentration in China using a regional 3D chemical transport model. We found that the impact on daily maximum eight-hour (MDA8) O3 concentration by the meteorological variation that mostly increased O3 was greater than that from emission reduction, which decreased O3. Specifically, the control measures implemented since 2013 in China have reduced SO2, NOx, PM2.5, and VOC emissions by 33%, 25%, 30%, and 4% in 2017, while NH3 emissions have increased by 7%. The changes in anthropogenic emissions lowered MDA8 O3 by 0.4–3.7 ppb (0.8%–7.6%, varying by region and month), although MDA8 O3 was increased slightly in some urban areas (i.e. North China) at the beginning/end of warm seasons. Relative to 2013, the average 2 m temperature in 2017 shows increments in North, North-east, East, and South China (0.34℃–0.83℃) and decreases in Central China (0.24℃). The average solar radiation shows increments in North, North-east, and South China (7.0–9.7 w/m2) and decreases in Central, South-west, and North-west China (4.7–10.3 w/m2). The meteorological differences significantly change MDA8 O3 by -3.5–8.5 ppb (-8.2%–18.8%) with large temporal variations. The average MDA8 O3 was slightly increased in North, North-east, East, and South China. The response surface model suggests that the O3 formation regime transfers from NOx-saturated in April to NOx-limited in July on average in China.

Keywords: O<sub>3sub> pollution     Meteorological influences     Emission reduction     NO<sub>xsub>     VOC    

CO<sub>2sub> capture using membrane contactors: a systematic literature review

Sanaa Hafeez, Tayeba Safdar, Elena Pallari, George Manos, Elsa Aristodemou, Zhien Zhang, S. M.

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 4,   Pages 720-754 doi: 10.1007/s11705-020-1992-z

Abstract: With fossil fuel being the major source of energy, CO emission levels need to be reduced to a minimal amount namely from anthropogenic sources. Energy consumption is expected to rise by 48% in the next 30 years, and global warming is becoming an alarming issue which needs to be addressed on a thorough technical basis. Nonetheless, exploring CO capture using membrane contactor technology has shown great potential to be applied and utilised by industry to deal with post- and pre-combustion of CO . A systematic review of the literature has been conducted to analyse and assess CO removal using membrane contactors for capturing techniques in industrial processes. The review began with a total of 2650 papers, which were obtained from three major databases, and then were excluded down to a final number of 525 papers following a defined set of criteria. The results showed that the use of hollow fibre membranes have demonstrated popularity, as well as the use of amine solvents for CO removal. This current systematic review in CO removal and capture is an important milestone in the synthesis of up to date research with the potential to serve as a benchmark databank for further research in similar areas of work. This study provides the first systematic enquiry in the evidence to research further sustainable methods to capture and separate CO .

Keywords: CO<sub>2sub> capture     preferred reporting items for systematic reviews and meta-analyses     membrane contactor    

A Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction temperature

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 6, doi: 10.1007/s11783-021-1425-3

Abstract:

• Cu<sub>0.15sub>-ACF performs the best for H<sub>2sub>S and PH<sub>3sub> simultaneous removal.

Keywords: ACF     H<sub>2sub>S     PH<sub>3sub>     Cu     Low temperature     Simultaneous removal    

Uncovering CO<sub>2sub> emission drivers under regional industrial transfer in China’s Yangtze River

Huijuan JIANG, Yong GENG, Xu TIAN, Xi ZHANG, Wei CHEN, Ziyan GAO

Frontiers in Energy 2021, Volume 15, Issue 2,   Pages 292-307 doi: 10.1007/s11708-020-0706-z

Abstract: With the relocation of heavy industries moving from downstream region to upstream and midstream regions in the Yangtze River Economic Belt (YREB), it is critical to encourage coordinated low carbon development in different regions within the YREB. This paper uncovers the evolution of CO emissions in different regions within the YREB for the period of 2000–2017. It decomposes regional CO emission changes using the temporal and cross-regional three-layer logarithmic mean Divisia index (LMDI) method. Besides, it decomposes industrial CO emission changes using the temporal two-layer LMDI method. The research results show that economic growth is the major driver for regional CO emission disparities. The mitigation drivers, such as energy intensity and energy structure, lead to a more decreased CO emission in the downstream region than in the upstream and midstream regions. In addition, it proposes several policy recommendations based upon the local realities, including improving energy efficiency, optimizing energy structure, promoting advanced technologies and equipment transfers, and coordinating the development in the upstream, midstream and downstream regions within the YREB.

Keywords: CO<sub>2sub> emission     multi-layer LMDI decomposition     industrial transfer     governance    

Title Author Date Type Operation

Efficient flower-like ZnSe/CuZnS photocatalyst for hydrogen production application

Journal Article

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

Journal Article

NO<sub>xsub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

Journal Article

Removal of P<sub>4sub>, PH<sub>3sub> and H<sub>2sub>S from Yellow Phosphoric Tail Gas by a Catalytic

Ning Ping,Hans-Jörg Bart,Wang Xueqian,Ma Liping,Chen Liang

Journal Article

Photoelectrocatalytic generation of H and S from toxic HS by using a novel BiOI/WO nanoflake array photoanode

Journal Article

Sulfur-deficient CoNi<sub>2sub>S<sub>4sub> nanoparticles-anchored porous carbon nanofibers as bifunctional

Journal Article

Inexpensive synthesis of a high-performance Fe

Imran, Muhammad S. Haider, Hee Taik Kim

Journal Article

Accounting for the uncertainties in the estimation of average shear wave velocity using – correlations

Journal Article

Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO decorated with ZnCdS

Journal Article

China’s pre-2020 CO

Hailin WANG

Journal Article

Highly effective visible-photocatalytic hydrogen evolution and simultaneous organic pollutant degradation over an urchin-like oxygen-doped MoS/ZnInS composite

Journal Article

Impacts of emissions and meteorological changes on China’s ozone pollution in the warm seasons of 2013

Dian Ding, Jia Xing, Shuxiao Wang, Xing Chang, Jiming Hao

Journal Article

CO<sub>2sub> capture using membrane contactors: a systematic literature review

Sanaa Hafeez, Tayeba Safdar, Elena Pallari, George Manos, Elsa Aristodemou, Zhien Zhang, S. M.

Journal Article

A Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction temperature

Journal Article

Uncovering CO<sub>2sub> emission drivers under regional industrial transfer in China’s Yangtze River

Huijuan JIANG, Yong GENG, Xu TIAN, Xi ZHANG, Wei CHEN, Ziyan GAO

Journal Article